Suspension and rheology guidance for pesticide suspension concentrates and emulsifiable concentrates.
Pesticide suspension concentrates combine solid active ingredients with water, dispersants and other formulation components. Dense particles can settle during storage when the continuous phase does not provide enough yield structure to resist gravity.
Water-dispersible organoclay hydrates and separates into a platelet structure in the aqueous phase. The hydrated platelets form a network that creates yield stress at rest. Under mixing or pouring shear, the structure breaks down enough for the product to flow; after shear stops, it rebuilds and helps slow particle movement.
A high Brookfield viscosity value alone does not prove that an SC will resist settling or redisperse easily. Formulators should also compare yield behaviour, settled-layer hardness, redispersibility and viscosity recovery after storage. The correct grade is the one that gives the finished formulation the required balance of storage stability and application flow.
| System | Recommended grade | Continuous phase | Polar activator | Product page |
|---|---|---|---|---|
| Water-based SC | CP-EW | Water | Not required | CP-EW |
| High-solids or high-density SC | CP-WBS | Water | Not required | CP-WBS |
| Solvent-based EC | CP-RL or CP-180 | Petroleum or aromatic solvent | Grade- and system-dependent; typically 20–30% of organoclay weight | CP-RL · CP-180 |
Do not use the same grade automatically in both systems. CP-EW and CP-WBS are designed for water-based dispersion. CP-RL and CP-180 are organically modified grades for organic solvent systems. Confirm the final selection with a laboratory screen in the actual formulation.
CP-EW is the standard starting point and forms a gel in water at concentrations of at least 2%. CP-WBS is intended for systems that require a stronger aqueous gel structure; its published viscosity is 10,000–13,000 mPa·s at 10% in water. High active-particle density, high solids or a demanding storage period may justify screening CP-WBS.
Solvent-based EC systems use a different chemistry. Pre-disperse the selected organically modified grade in the solvent, then follow the grade-specific activation and high-shear procedure. Do not add a solvent-based grade directly to the water phase and expect the same hydration behaviour as CP-EW or CP-WBS.
Use 2–6 wt% of the total formulation as the development range for SC and EC screening. Do not treat the range as a guaranteed commercial dosage. The optimum level depends on active-particle density, total solids, dispersant package, solvent or water phase, pH, temperature and required storage period.
| Formulation type | Development range | Primary function | Screening note |
|---|---|---|---|
| Suspension concentrate (SC) | 2–6 wt% of total formulation | Suspension and yield structure | Higher solids and denser active particles may require screening toward the upper end |
| Suspo-emulsion (SE) | 2–6 wt% of total formulation | Suspension support and flow control | Check compatibility with both the dispersed solid and emulsion phase |
| Emulsifiable concentrate (EC) | 2–6 wt% of total formulation | Rheology and phase stability | Use an organically modified grade and verify activator compatibility |
| WP / WDG slurry or premix | 2–6 wt% of total formulation | Suspension during preparation and storage | Test wetting, grind quality and redispersibility in the intended process |
A practical screening design is 2%, 3%, 4%, 5% and 6%, followed by measurements of yield behaviour, viscosity, 30-day static settling, hard-cake formation and redispersibility. Keep the same weight basis and test procedure across all samples.
Do not add a polar activator to the water-based SC procedure. CP-EW and CP-WBS are selected for direct water dispersion.
Use ethanol where methanol is restricted by the customer’s process or compliance requirements. The activator percentage is based on organoclay weight, not total formulation weight.
CP-EW and CP-WBS have a published optimal pH range of 7.0–8.0. Because agrochemical formulations can contain acidic or alkaline auxiliaries, measure pH after the full formulation is assembled. If the system falls outside the working range, recheck hydration and yield structure before increasing the clay dosage.
| Symptom | Likely cause | Fix |
|---|---|---|
| Hard cake after storage | Insufficient yield structure, unsuitable grade or incomplete dispersion | Confirm the continuous phase, review grade selection and repeat the 2–6 wt% screen with controlled hydration or activation |
| Settling but easy redispersion | Soft sediment may be acceptable for the product specification | Define the customer’s redispersibility requirement and compare the same storage and mixing protocol across samples |
| Viscosity too high to pour or spray | Dosage or gel strength is higher than the process requires | Screen a lower level while checking settling, application flow and viscosity recovery |
| No viscosity increase | Wrong grade, incomplete hydration, unsuitable pH or incorrect activation sequence | Use a water grade in SC, check pH 7.0–8.0, or review solvent wetting and activation in EC |
| Viscosity falls after hot storage | Clay network is not stable in the finished system or the formulation changes with temperature | Compare grades using matched accelerated-storage samples and measure viscosity before and after storage |
| Particles or agglomerates after mixing | Powder was added too late, wetting was incomplete or a solvent grade was used in water | Hydrate CP-EW or CP-WBS before adding the active slurry; use an organically modified grade only in the solvent phase |
Related technical resources: CP-EW technical data · CP-WBS technical data · CP-RL technical data · CP-180 technical data · Anti-settling guidance · How organoclay works
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